Issue 16, 2018, Issue in Progress
From the journal:

RSC Advances

C–C and C–H coupling reactions by Fe3O4/KCC-1/APTPOSS supported palladium-salen-bridged ionic networks as a reusable catalyst

Asadollah Hassankhani,*a   Seyed Mohsen Sadeghzadeh ORCID logo b  and  Rahele Zhianib  

* Corresponding authors

a Department of New Materials, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, PO Box 76315-117, Kerman, Iran
E-mail: ahassankhani@gmail.com

b Young Researchers and Elite Club, Neyshabur Branch, Islamic Azad University, Neyshabur, Iran

Abstract

This study investigates the potential application of an efficient, easily recoverable and reusable magnetically separable Fe3O4/KCC-1/APTPOSS nanoparticle-supported salen/Pd(II) catalyst for C–C and C–H cross-couplings. The Fe3O4/KCC-1/APTPOSS/salen/Pd(II) MNPs were thoroughly characterized by using TEM, FE-SEM, TGA, XRD, VSM, FT-IR, ICP-MS, and BET. This observation was exploited in the direct and selective chemical reaction of 2-acetyl-benzaldehyde with cyclopentadiene for the synthesis of pentafulvene. The recycled catalyst has been analyzed by ICP-MS showing only minor changes in the morphology after the reaction, thus confirming the robustness of the catalyst.

Graphical abstract: C–C and C–H coupling reactions by Fe3O4/KCC-1/APTPOSS supported palladium-salen-bridged ionic networks as a reusable catalyst

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Article information

DOI
https://doi.org/10.1039/C8RA00485D
Article type
Paper
Submitted
17 Jan 2018
Accepted
20 Feb 2018
First published
26 Feb 2018
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2018,8, 8761-8769

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C–C and C–H coupling reactions by Fe3O4/KCC-1/APTPOSS supported palladium-salen-bridged ionic networks as a reusable catalyst

A. Hassankhani, S. M. Sadeghzadeh and R. Zhiani, RSC Adv., 2018, 8, 8761 DOI: 10.1039/C8RA00485D

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