Tuning the structure and properties of a multiferroic metal–organic-framework via growing under high magnetic fields

Lin Hu; Zhe Wang; Hui Wang; Zhe Qu; Qianwang Chen

doi:10.1039/C8RA00799C

Tuning the structure and properties of a multiferroic metal–organic-framework via growing under high magnetic fields†

Lin Hu,

‡^ac Zhe Wang,‡^a Hui Wang,

^a Zhe Qu*^a and Qianwang Chen

*^ab

Author affiliations

* Corresponding authors

^a Anhui Province Key Laboratory of Condensed Matter Physics at Extreme Conditions, High Magnetic Field Laboratory, Chinese Academy of Sciences, Hefei 230031, Anhui, China
E-mail: zhequ@hmfl.ac.cn

^b Hefei National Laboratory for Physical Science at Microscale, Department of Materials Science & Engineering, Collaborative Center of Suzhou Nano Science and Technology, University of Science and Technology of China, Hefei 230026, China
E-mail: cqw@ustc.edu.cn

^c Key Laboratory of Photovoltaic and Energy Conservation Materials, Institute of Applied Technology, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China

Abstract

High magnetic field-induced synthesis has been demonstrated to tune the structure and properties of the multiferroic metal–organic framework [(CH₃)₂NH₂][Mn(HCOO)₃]. The crystals obtained under 90 kOe exhibit a lower ferroelectric polarization value and reduced magnetic susceptibility, compared to crystals obtained without a field, which is attributed to structural changes induced by the high magnetic field.

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DOI: https://doi.org/10.1039/C8RA00799C
Article type: Paper
Submitted: 26 Jan 2018
Accepted: 02 Apr 2018
First published: 12 Apr 2018
This article is Open Access

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RSC Adv., 2018,8, 13675-13678

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Tuning the structure and properties of a multiferroic metal–organic-framework via growing under high magnetic fields

L. Hu, Z. Wang, H. Wang, Z. Qu and Q. Chen, RSC Adv., 2018, 8, 13675 DOI: 10.1039/C8RA00799C

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Tuning the structure and properties of a multiferroic metal–organic-framework via growing under high magnetic fields†

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Tuning the structure and properties of a multiferroic metal–organic-framework via growing under high magnetic fields

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