Surface modification of carbon nanotubes by using iron-mediated activators generated by electron transfer for atom transfer radical polymerization

Abstract

Herein, a surface-initiated activator generated by electron transfer for an atom transfer radical polymerization (AGET ATRP) system was developed on the surface of multiwall carbon nanotubes (MWCNTs) by using FeCl₃·6H₂O as the catalyst, tris-(3,6-dioxoheptyl) amine (TDA-1) as the ligand and ascorbic acid (AsAc) as the reducing agent. A wide range of polymers, such as polystyrene (PS), poly(methyl methacrylate) (PMMA) and poly(poly(ethylene glycol) methyl ether methacrylate) (PPEGMA), were successfully grafted onto the surfaces. The core–shell structure of MWCNTs@PS was observed by TEM. Both Raman spectra and the results of hydrolysis of MWCNTs@PS (after extraction by THF) confirmed that the PS chains were covalently tethered onto the surfaces of the MWCNTs. Due to superior biocompatibility of the iron catalyst, the strategy of modification of MWCNTs via iron-mediated AGET ATRP provided a promising method for the controllable and biocompatible modification of nanomaterials.