Synchronous, efficient and fast removal of phosphate and organic matter by carbon-coated lanthanum nanorods

Abstract

Both phosphate and organic carbon can serve as nutrients for microorganism growth. Simultaneous removal of both nutrients would realize the antibacterial strategy of nutrient starvation better to ensure water quality safety. In addition, a short treatment time is the premise for the application of a material in water treatment. Herein, carbon-coated lanthanum nanorods with a uniform distribution of La and C (C–La-MOF) were rationally prepared through glucose and La-MOF hydrothermal treatment and further carbonization to synchronously and rapidly remove phosphate and organic matter. The carbon layer thickness was tuned by varying the hydrothermal time to find the optimal balance between excellent phosphate intake and low lanthanum leakage. C–La-MOF had a strong anti-interference ability and high phosphate capture capacity over a wide pH range of 2–12. Impressively, when phosphate and organic carbon coexisted in solution, their removal performances remained relatively unchanged compared with that when the two nutrients existed independently, and their adsorption equilibriums could be easily reached within 10 min. All of the above results prove that C–La-MOF is a promising material for practical drinking water treatment.