Predicting sulfur solubility in hydrogen sulfide, carbon dioxide, and methane with an improved thermodynamic model

Abstract

During development of high sulfur-content natural gas fields, gaseous sulfur is likely to precipitate and deposit in the reservoir and transmission pipelines owing to changes in the temperature, pressure, and gas components. It is important to accurately predict the elemental sulfur solubility in hydrogen sulfide, carbon dioxide, and methane because these are the three main components of high-sulfur-content natural gas. The binary interaction coefficients between sulfur and hydrogen sulfide, carbon dioxide, and methane are the key parameters for predicting the sulfur solubility with a thermodynamic model. In this work, we show that the binary interaction coefficients are not constant, but temperature dependent. Three-parameter temperature-dependent equations for the binary interaction coefficients between sulfur and solvents are proposed. The corresponding regression equations for calculating the binary interaction coefficients between sulfur and hydrogen sulfide, carbon dioxide, and methane are obtained using experimental sulfur solubility data. The average relative errors of the sulfur solubility predicted using the experimental data in hydrogen sulfide, carbon dioxide, and methane using the thermodynamic model with the improved binary interaction coefficients are 6.30%, 1.69%, and 4.34%, and the average absolute relative errors are 7.90%, 13.12%, and 14.98%, respectively. Comparing the improved binary interaction coefficients with four other sets of reported values shows that the solubility values predicted by the thermodynamic model with improved binary interaction coefficients fit the experimental data better.