Four 3D coordination polymers based on layers with single syn–anti carboxylate bridges: synthesis, structures, and magnetic properties

Abstract

Four novel coordination polymers (CPs) based on a new 4-(3,5-dicarboxylphenyl) picolinic acid ligands (H₃L), [M₃(L)₂(H₂O)₆]·4H₂O (M₃ = Mn₃, 1; Co₃, 2; Ni₃, 3, Co_1.01Ni_1.99, 4), have been hydrothermally synthesized, and structurally and magnetically characterized. In these isomorphous CPs, octahedrally coordinated metal ions are linked by the single syn–anti carboxylate bridge (μ-COO) to give linear trinuclear motifs. The motifs are connected through the other single syn–anti carboxylate bridge (μ-COO) to give a 2D (4,4) layer, and the layers are interlinked by the L ligands into 3D frameworks. Magnetic measurement indicates that antiferromagnetic interactions between metal ions are mediated through the single syn–anti carboxylate bridges in 1 and 2, while the same carboxylate bridges in 3 transmit ferromagnetic couplings. The bimetallic CP 4 shows interesting complicated magnetic behaviors due to the competition effect of Co(II) and Ni(II) ions.