Effects of calcium ion and pH on the adsorption/regeneration process by activated carbon permeable reactive barriers

Abstract

Activated carbon (AC) is widely used in groundwater remediation, more specifically, for the activated carbon permeable barriers (AC-PRBs). However, the long-term use of AC-PRBs is limited by the AC's adsorption capacity. In this work, a Fenton-combined persulfate system (Fe²⁺/H₂O₂/S₂O₈²⁻) was used to treat activated carbon that was saturated with organic compounds, such as trichloroethylene (TCE), to promote the oxidation of the adsorbed contaminants and the regeneration of AC. The effect of pH and the calcium ion (Ca²⁺) were investigated during AC's adsorption/regeneration. The results showed that under certain reaction conditions (TCE/Fe²⁺/H₂O₂/S₂O₈²⁻ molar ratio of 1.00/9.00/56.63/76.25), acidic pH conditions (pH = 3) favored the adsorption/regeneration process of AC, yielding a regeneration efficiency of 26.28% on average in three regeneration cycles. The presence of Ca²⁺, even in relatively low concentrations, seemed to decrease HO˙ generation and AC's adsorption capacity.