1,3-Phenylene-bridged naphthalene wheels synthesized by one-pot Suzuki–Miyaura coupling and the complex of the hexamer with C60

Peifeng Mei; Akinobu Matsumoto; Hironobu Hayashi; Mitsuharu Suzuki; Naoki Aratani; Hiroko Yamada

doi:10.1039/C8RA03601B

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1,3-Phenylene-bridged naphthalene wheels synthesized by one-pot Suzuki–Miyaura coupling and the complex of the hexamer with C₆₀†

Peifeng Mei,^a Akinobu Matsumoto,^a Hironobu Hayashi,

^a Mitsuharu Suzuki,

^a Naoki Aratani

*^a and Hiroko Yamada

*^a

Author affiliations

* Corresponding authors

^a Graduate School of Science and Technology, Nara Institute of Science and Technology (NAIST), Takayama-cho, Ikoma, Nara 630-0192, Japan
E-mail: aratani@ms.naist.jp, hyamada@ms.naist.jp

Abstract

A large 1,3-phenylene-bridged hexameric naphthalene wheel N6 and a heptameric wheel N7 were synthesized simply by Suzuki–Miyaura coupling via one-pot reaction from monomers. We could control the distribution of N6 and N7 via the reaction conditions. The hexameric wheel structure was revealed by X-ray diffraction analysis. The wheel N6 exhibited C₆₀ encapsulation ability in the solid state, which was also confirmed by single crystal X-ray analysis.

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Article information

DOI: https://doi.org/10.1039/C8RA03601B
Article type: Paper
Submitted: 26 Apr 2018
Accepted: 01 Jun 2018
First published: 07 Jun 2018
This article is Open Access

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RSC Adv., 2018,8, 20872-20876

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1,3-Phenylene-bridged naphthalene wheels synthesized by one-pot Suzuki–Miyaura coupling and the complex of the hexamer with C₆₀

P. Mei, A. Matsumoto, H. Hayashi, M. Suzuki, N. Aratani and H. Yamada, RSC Adv., 2018, 8, 20872 DOI: 10.1039/C8RA03601B

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