Mechanism of adsorption of humic acid by modified aged refuse

Abstract

In the present study, aged refuse (AR) was modified to be applied as an adsorbent to remove humic acid from water. The efficiency of humic acid removal by modified aged refuse (MAR) under different preparation conditions (calcination temperature, dose of aged refuse for calcination and holding time) was systematically investigated. Results showed that the optimum preparation conditions are calcination temperature = 700 °C, AR dose for calcination = 25 g, and holding time = 2.0 h. The characteristics of the modified aged refuse obtained under different calcination conditions were determined by Fourier transform infrared, X-ray diffraction and X-ray photoelectron spectroscopy analysis. In addition, the effects of modified aged refuse dose and initial solution pH on adsorption performance were studied. The removal of humic acid increased with higher doses of modified aged refuse, and weak alkaline (initial pH = 8.0) conditions were favorable for humic acid removal. A pseudo-second order model fitted the experimental data well. Moreover, the adsorption isotherms were well described by the Langmuir isotherm model, in which the monolayer surface loading was calculated to be approximately 37 mg g⁻¹. During the adsorption process, the molecular weight, degree of condensation and aromaticity of humic acid were considerably decreased, according to 3D-EEM analysis. MAR as a new type of adsorbent thus provides a potential adsorption method for humic acid.