Issue 55, 2018, Issue in Progress

Advanced binder-free electrodes based on CoMn2O4@Co3O4 core/shell nanostructures for high-performance supercapacitors

Abstract

Three-dimensional (3D) hierarchical CoMn2O4@Co3O4 core/shell nanoneedle/nanosheet arrays for high-performance supercapacitors were designed and synthesized on Ni foam by a two-step hydrothermal route. The hybrid nanostructure exhibits much more excellent capacitive behavior compared with either the pristine CoMn2O4 nanoneedle arrays alone or Co3O4 nanosheets alone. The formation of an interconnected pore hybrid system is quite beneficial for the facile electrolyte penetration and fast electron transport. The CoMn2O4@Co3O4 electrode can achieve a high specific capacitance of 1627 F g−1 at 1 A g−1 and 1376 F g−1 at 10 A g−1. In addition, an asymmetric supercapacitor (ASC) was assembled by using the CoMn2O4@Co3O4 core/shell hybrid nanostructure arrays on Ni foam as a positive electrode and activated carbon as a negative electrode in an aqueous 3 M KOH electrolyte. A specific capacitance of 125.8 F g−1 at 1 A g−1 (89.2% retention after 5000 charge/discharge cycles at a current density of 2 A g−1) and a high energy density of 44.8 W h kg−1 was obtained. The results indicate that the obtained unique integrated CoMn2O4@Co3O4 nanoarchitecture may show great promise as ASC electrodes for potential applications in energy storage.

Graphical abstract: Advanced binder-free electrodes based on CoMn2O4@Co3O4 core/shell nanostructures for high-performance supercapacitors

Supplementary files

Article information

Article type
Paper
Submitted
25 Jul 2018
Accepted
04 Sep 2018
First published
10 Sep 2018
This article is Open Access
Creative Commons BY license

RSC Adv., 2018,8, 31594-31602

Advanced binder-free electrodes based on CoMn2O4@Co3O4 core/shell nanostructures for high-performance supercapacitors

X. Chen, X. Liu, Y. Liu, Y. Zhu, G. Zhuang, W. Zheng, Z. Cai and P. Yang, RSC Adv., 2018, 8, 31594 DOI: 10.1039/C8RA06289G

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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