Issue 36, 2018
From the journal:

Chemical Science

A mild light-induced cleavage of the S–O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes†

Maxim Ratushnyy,a   Monika Kamenovaa  and  Vladimir Gevorgyan ORCID logo *a  

* Corresponding authors

a Department of Chemistry, University of Illinois at Chicago, 845 W. Taylor St., Room 4500 SES, Chicago, Illinois 60607, USA
E-mail: vlad@uic.edu

Abstract

A new mode of S–O bond activation has been discovered, which constitutes novel reactivity of easily available and bench-stable arylsulfonate phenol esters. This protocol enables access to putative sulfonyl radical intermediates, which enable straightforward access to valuable vinyl sulfones.

Graphical abstract: A mild light-induced cleavage of the S–O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes

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Article information

DOI
https://doi.org/10.1039/C8SC02769B
Article type
Edge Article
Submitted
24 Jun 2018
Accepted
23 Jul 2018
First published
25 Jul 2018
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2018,9, 7193-7197

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A mild light-induced cleavage of the S–O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes

M. Ratushnyy, M. Kamenova and V. Gevorgyan, Chem. Sci., 2018, 9, 7193 DOI: 10.1039/C8SC02769B

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