Issue 29, 2018

Laser filament bottom-up growth sintering for multi-planar diffraction-limit printing and its application to ultra-transparent wearable thermo-electronics

Abstract

We report a novel cost-effective digital fabrication method for the production of high resolution electrodes of 1 μm-grade width on multiple planes connected at an angle using an affordable light source. This was achieved by the laser filament growth sintering of nanoseed/organometallic hybrid precursors, which were reformulated from a low-cost, particle-free, ionic organometallic solution. Growth sintering of the hybrid precursor, which creates solid electrodes through the sequential thermo-chemical interactions of nucleation, clustering, thermal growth, and aggregation, improves the conductivity and resolution of the electrodes via bottom-up thermal crystallization and stable chemical transition processes. The laser filament with a Bessel profile, which was modulated from a conventional low-cost laser with a Gaussian profile, localizes the growth sintering interaction within a transversely elongated focusing area close to the diffraction limit, unlike the very narrow focusing area in typical laser optics. As a result, this method enabled the fabrication of an ultra-transparent conductor with a transmittance of more than 97% in the visible spectrum. The electrodes were completely invisible to the naked eye, even when viewed at close range. A transparent micro-heater for humidity-free smart glasses was successfully fabricated to demonstrate the potential of one-step manufacturing of functional wearable devices.

Graphical abstract: Laser filament bottom-up growth sintering for multi-planar diffraction-limit printing and its application to ultra-transparent wearable thermo-electronics

Supplementary files

Article information

Article type
Paper
Submitted
22 Apr 2018
Accepted
18 Jun 2018
First published
18 Jun 2018

J. Mater. Chem. C, 2018,6, 7759-7766

Laser filament bottom-up growth sintering for multi-planar diffraction-limit printing and its application to ultra-transparent wearable thermo-electronics

S. Kwon, S. Back, J. E. Park and B. Kang, J. Mater. Chem. C, 2018, 6, 7759 DOI: 10.1039/C8TC01915K

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