Rhodium(III) vs. cobalt(III): a mechanistically distinct three-component C–H bond addition cascade using a Cp*RhIII catalyst

Ruirui Li; Cheng-Wei Ju; Dongbing Zhao

doi:10.1039/C8CC08792J

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Rhodium(iii) vs. cobalt(iii): a mechanistically distinct three-component C–H bond addition cascade using a Cp*Rh^III catalyst†

Ruirui Li,^a Cheng-Wei Ju^a and Dongbing Zhao

*^a

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* Corresponding authors

^a State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, China
E-mail: dongbing.chem@nankai.edu.cn

Abstract

Three-component C–H bond additions across two different coupling partners remain underdeveloped. Herein, we report the first three-component Rh^III-catalyzed C–H bond additions to a wide range of dienes and aldehydes. Our method constitutes a complementary access with Ellman's Co^III-catalytic system to homoallylic alcohols.

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Article information

DOI: https://doi.org/10.1039/C8CC08792J
Article type: Communication
Submitted: 04 Nov 2018
Accepted: 07 Dec 2018
First published: 08 Dec 2018

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Chem. Commun., 2019,55, 695-698

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Rhodium(III) vs. cobalt(III): a mechanistically distinct three-component C–H bond addition cascade using a Cp*Rh^III catalyst

R. Li, C. Ju and D. Zhao, Chem. Commun., 2019, 55, 695 DOI: 10.1039/C8CC08792J

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