Electrochemically driven interfacial halogen bonding on self-assembled monolayers for anion detection

Hussein Hijazi; Antoine Vacher; Sihem Groni; Dominique Lorcy; Eric Levillain; Claire Fave; Bernd Schöllhorn

doi:10.1039/C8CC08856J

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Electrochemically driven interfacial halogen bonding on self-assembled monolayers for anion detection†

Hussein Hijazi,

^a Antoine Vacher,

^b Sihem Groni,

^a Dominique Lorcy,

^b Eric Levillain,

^c Claire Fave

*^a and Bernd Schöllhorn

*^a

Author affiliations

* Corresponding authors

^a Laboratoire d’Electrochimie Moléculaire, UMR CNRS 7591, Université Paris Diderot, Sorbonne Paris Cité, 15 rue Jean-Antoine de Baïf, F-75205 Paris Cedex 13, France
E-mail: claire.fave@univ-paris-diderot.fr, bernd.schollhorn@univ-paris-diderot.fr

^b Univ Rennes, CNRS, ISCR Institut des Sciences Chimiques de Rennes – UMR 6226, F-35000 Rennes, France

^c MOLTECH Anjou, UMR CNRS 6200, Univ d'Angers, 2 Bd Lavoisier, F-49045 ANGERS Cedex, France

Abstract

Electrochemically driven interfacial halogen bonding between redox-active SAMs and halide anions was quantitatively studied for the first time. The halogen bond donor properties were switched on by electrochemically controlling the oxidation state of the adsorbates. Experimental data and simulation show high binding enhancement towards halide anions compared to homogeneous systems.

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Article information

DOI: https://doi.org/10.1039/C8CC08856J
Article type: Communication
Submitted: 06 Nov 2018
Accepted: 21 Jan 2019
First published: 22 Jan 2019

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Chem. Commun., 2019,55, 1983-1986

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Electrochemically driven interfacial halogen bonding on self-assembled monolayers for anion detection

H. Hijazi, A. Vacher, S. Groni, D. Lorcy, E. Levillain, C. Fave and B. Schöllhorn, Chem. Commun., 2019, 55, 1983 DOI: 10.1039/C8CC08856J

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Chemical Communications

Electrochemically driven interfacial halogen bonding on self-assembled monolayers for anion detection†

Abstract

Supplementary files

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Electrochemically driven interfacial halogen bonding on self-assembled monolayers for anion detection

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