Issue 13, 2019
From the journal:

Chemical Communications

Controlled Ni-catalyzed mono- and double-decarbonylations of α-ketothioesters†

Zhao-Jing Zheng,a   Cheng Jiang,b   Peng-Cheng Shao,b   Wen-Fei Liu,b   Tian-Tian Zhao,b   Peng-Fei Xu ORCID logo *a  and  Hao Wei ORCID logo *b  

* Corresponding authors

a State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

b Key Laboratory of Synthetic and Natural Functional Molecular Chemistry of the Ministry of Education, National Demonstration Center for Experimental Chemistry Education (Northwest University), College of Chemistry & Materials Science, Northwest University, Xi’an 710127, China

Abstract

A method for Ni-catalyzed controlled decarbonylation of α-ketothioesters is described. Mono- and double-decarbonylations, which gave thioesters and thioethers, respectively, were selectively achieved by changing the ligand. A fundamental study of Ni-catalyzed decarbonylation of α-ketothioesters is presented.

Graphical abstract: Controlled Ni-catalyzed mono- and double-decarbonylations of α-ketothioesters

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C8CC09352K
Article type
Communication
Submitted
24 Nov 2018
Accepted
16 Jan 2019
First published
17 Jan 2019

Chem. Commun., 2019,55, 1907-1910

Permissions

Request permissions

Controlled Ni-catalyzed mono- and double-decarbonylations of α-ketothioesters

Z. Zheng, C. Jiang, P. Shao, W. Liu, T. Zhao, P. Xu and H. Wei, Chem. Commun., 2019, 55, 1907 DOI: 10.1039/C8CC09352K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements