Issue 9, 2019

Li4Na2CsB7O14: a new edge-sharing [BO4]5− tetrahedra containing borate with high anisotropic thermal expansion

Abstract

Li4Na2CsB7O14 with unique edge-sharing [BO4]5− tetrahedra, an unprecedented [B14O28]14− cluster, and high anisotropic thermal expansion has been obtained under atmospheric pressure conditions, indicating that high pressure is not essential for obtaining edge-sharing [BO4]5− tetrahedra-containing borates. In addition, Li4Na2CsB7O14 may be used as a thermal expansion material.

Graphical abstract: Li4Na2CsB7O14: a new edge-sharing [BO4]5− tetrahedra containing borate with high anisotropic thermal expansion

Supplementary files

Article information

Article type
Communication
Submitted
27 Nov 2018
Accepted
24 Dec 2018
First published
26 Dec 2018

Chem. Commun., 2019,55, 1295-1298

Li4Na2CsB7O14: a new edge-sharing [BO4]5− tetrahedra containing borate with high anisotropic thermal expansion

M. Mutailipu, M. Zhang, H. Li, X. Fan, Z. Yang, S. Jin, G. Wang and S. Pan, Chem. Commun., 2019, 55, 1295 DOI: 10.1039/C8CC09422E

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