Issue 17, 2019

Dual-cubic-cage based lanthanide sulfate–carboxylpyrazolate frameworks with high hydrolytic stability and remarkable proton conduction

Abstract

We report herein a series of lanthanide sulfate–carboxylpyrazolate frameworks based on double cuboid cavities that are highly hot-water stable, and have room-temperature proton conductivity of over 10−3 S cm−1 at 97% relative humidity without any appreciable loss of performance for at least three recycling times, ranking among the best lanthanide-based coordination frameworks.

Graphical abstract: Dual-cubic-cage based lanthanide sulfate–carboxylpyrazolate frameworks with high hydrolytic stability and remarkable proton conduction

Supplementary files

Article information

Article type
Communication
Submitted
28 Nov 2018
Accepted
31 Jan 2019
First published
31 Jan 2019

Chem. Commun., 2019,55, 2497-2500

Dual-cubic-cage based lanthanide sulfate–carboxylpyrazolate frameworks with high hydrolytic stability and remarkable proton conduction

L. He, J. K. Nath, E. Chen, H. Lai, S. Huang and Q. Lin, Chem. Commun., 2019, 55, 2497 DOI: 10.1039/C8CC09474H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements