Intermolecular, redox-neutral azidoarylation of alkenes via photoredox catalysis

Jian Chen; Shengqing Zhu; Jian Qin; Lingling Chu

doi:10.1039/C9CC00241C

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Intermolecular, redox-neutral azidoarylation of alkenes via photoredox catalysis†

Jian Chen,‡^a Shengqing Zhu,‡^a Jian Qin^a and Lingling Chu

*^a

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* Corresponding authors

^a State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-Dimension Materials, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
E-mail: lingling.chu1@dhu.edu.cn

Abstract

An intermolecular, redox-neutral azidoarylation of alkenes with pyridines and TMSN₃ has been reported via visible light-induced photoredox catalysis. This protocol utilized a radical addition/radical coupling sequence, allowing for facile and regioselective installation of versatile β-azido pyridines under redox-neutral and mild conditions.

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Article information

DOI: https://doi.org/10.1039/C9CC00241C
Article type: Communication
Submitted: 10 Jan 2019
Accepted: 01 Feb 2019
First published: 01 Feb 2019

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Chem. Commun., 2019,55, 2336-2339

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Intermolecular, redox-neutral azidoarylation of alkenes via photoredox catalysis

J. Chen, S. Zhu, J. Qin and L. Chu, Chem. Commun., 2019, 55, 2336 DOI: 10.1039/C9CC00241C

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Chemical Communications

Intermolecular, redox-neutral azidoarylation of alkenes via photoredox catalysis†

Abstract

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Intermolecular, redox-neutral azidoarylation of alkenes via photoredox catalysis

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