Issue 57, 2019

Dysprosium complexes bearing unsupported DyIII–GeII/SnII metal–metal bonds as single-ion magnets

Abstract

Two dysprosium complexes bearing unsupported Dy–Ge/Sn metal–metal bonds are reported here, wherein the Dy–Ge and Dy–Sn bonds both contain relatively large covalency. The complexes exhibit slow relaxation of magnetization at zero field with energy barriers of 485 and 620 K, respectively, and the blocking temperature of 6 K.

Graphical abstract: Dysprosium complexes bearing unsupported DyIII–GeII/SnII metal–metal bonds as single-ion magnets

Supplementary files

Article information

Article type
Communication
Submitted
12 Mar 2019
Accepted
17 Jun 2019
First published
17 Jun 2019

Chem. Commun., 2019,55, 8250-8253

Dysprosium complexes bearing unsupported DyIII–GeII/SnII metal–metal bonds as single-ion magnets

S. Chen, J. Xiong, Y. Zhang, F. Ma, H. Sun, B. Wang and S. Gao, Chem. Commun., 2019, 55, 8250 DOI: 10.1039/C9CC00388F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements