Issue 32, 2019
From the journal:

Chemical Communications

The phenomenon of conversion polymorphism in Bi-containing metastable perovskites†

Dmitry D. Khalyavin, ORCID logo *a   Andrei N. Salak, ORCID logo *b   Elena L. Fertman,c   Oleksandr V. Kotlyar,c   Edwin Eardley,d   Nikolai M. Olekhnovich,e   Anatoli V. Pushkarev,e   Yury V. Radyush,e   Alexey V. Fedorchenko, ORCID logo c   Vladimir A. Desnenko,c   Pascal Manuel,a   Lei Ding, ORCID logo a   Erik Čižmár ORCID logo f  and  Alexander Feherf  

* Corresponding authors

a ISIS Facility, Rutherford Appleton Laboratory, Harwell Oxford, Didcot OX11 0QX, UK
E-mail: dmitry.khalyavin@stfc.ac.uk

b Department of Materials and Ceramics Engineering and CICECO – Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal
E-mail: salak@ua.pt

c B. Verkin Institute for Low Temperature Physics and Engineering of NAS of Ukraine, 61103 Kharkov, Ukraine

d Element Six UK Ltd, Global Innovation Centre, Harwell Oxford, OX11 0QR Didcot, UK

e Scientific-Practical Materials Research Centre of NAS of Belarus, 220072 Minsk, Belarus

f Faculty of Science, P. J. Šafárik University in Košice, 04154 Košice, Slovakia

Abstract

A post-synthesis thermal treatment of metastable phases in the high-pressure stabilised perovskite BiFe1−yScyO3 system results in the irreversible formation of polymorphs which represent novel polar and antipolar structures with interesting magnetic properties. Such annealing-stimulated polymorphism is believed to be a general phenomenon which can be found in other systems.

Graphical abstract: The phenomenon of conversion polymorphism in Bi-containing metastable perovskites

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C9CC00472F
Article type
Communication
Submitted
18 Jan 2019
Accepted
25 Mar 2019
First published
26 Mar 2019

Chem. Commun., 2019,55, 4683-4686

Permissions

Request permissions

The phenomenon of conversion polymorphism in Bi-containing metastable perovskites

D. D. Khalyavin, A. N. Salak, E. L. Fertman, O. V. Kotlyar, E. Eardley, N. M. Olekhnovich, A. V. Pushkarev, Y. V. Radyush, A. V. Fedorchenko, V. A. Desnenko, P. Manuel, L. Ding, E. Čižmár and A. Feher, Chem. Commun., 2019, 55, 4683 DOI: 10.1039/C9CC00472F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements