Issue 24, 2019
From the journal:

Chemical Communications

Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis†

Veera Reddy Yatham,a   Peter Bellotti ORCID logo a  and  Burkhard König ORCID logo *a  

* Corresponding authors

a Institut für Organische Chemie, Fakultät für Chemie und Pharmazie, Universität Regensburg, Universitätstraße 31, D-93053 Regensburg, Germany
E-mail: Burkhard.Koenig@chemie.uni-regensburg.de
Tel: +49-941-943-4547

Abstract

We report the cerium photocatalyzed radical decarboxylative hydrazination of carboxylic acids with di-tert-butylazodicarboxylate (DBAD). The operationally simple protocol provides rapid access to synthetically useful hydrazine derivatives and overcomes current scope limitations in the photoredox-catalyzed decarboxylation of carboxylic acids.

Graphical abstract: Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis

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Article information

DOI
https://doi.org/10.1039/C9CC00492K
Article type
Communication
Submitted
21 Jan 2019
Accepted
12 Feb 2019
First published
04 Mar 2019
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2019,55, 3489-3492

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Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis

V. R. Yatham, P. Bellotti and B. König, Chem. Commun., 2019, 55, 3489 DOI: 10.1039/C9CC00492K

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