Chiral carbazole-based BODIPYs with a binaphthyl unit were synthesized via an Al-mediated reaction. Et2AlCl was found to be a convenient reagent for the reaction to give the chiral BODIPYs in high yields. It has been shown for the first time that these chiral carbazole-based BODIPYs show circularly polarized luminescence (CPL) both in solution and in the solid state.
C. Maeda, K. Nagahata, K. Takaishi and T. Ema, Chem. Commun., 2019, 55, 3136 DOI: 10.1039/C9CC00894B
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