Issue 30, 2019
From the journal:

Chemical Communications

A photochemical route to a square planar, ruthenium(iv)-bis(imide)†

Kelly E. Aldrich ORCID logo a  and  Aaron L. Odom ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Michigan State University, 578 S Shaw Ln, East Lansing, MI, USA
E-mail: odom@chemistry.msu.edu

Abstract

The square planar, ruthenium(IV) bis(imide) trans-Ru(NAr)2(PMe3)2 can be prepared photochemically from a Ru(II) tetrazene. Additionally, we report reactivity of the Ru(IV) bis(imide) species, similar to that of the osmium derivative. Attempts to change both imide group and phosphine substituents are presented, which led to alternative reactivity.

Graphical abstract: A photochemical route to a square planar, ruthenium(iv)-bis(imide)

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Article information

DOI
https://doi.org/10.1039/C9CC01019J
Article type
Communication
Submitted
03 Feb 2019
Accepted
16 Mar 2019
First published
27 Mar 2019

Chem. Commun., 2019,55, 4403-4406

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A photochemical route to a square planar, ruthenium(IV)-bis(imide)

K. E. Aldrich and A. L. Odom, Chem. Commun., 2019, 55, 4403 DOI: 10.1039/C9CC01019J

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