The first rhodium-containing oxide-hydride phases, LaSrCo0.5Rh0.5O3H and La0.5Sr1.5Mn0.5Rh0.5O3H, have been prepared via topochemical anion exchange. This clearly demonstrates the ability of rhodium, a late 4d transition metal, to kinetically stabilize oxide-hydride lattices, reinforcing the paradigm of covalent stabilization of transition-metal oxide-hydride phases.
L. Jin and M. A. Hayward, Chem. Commun., 2019, 55, 4861 DOI: 10.1039/C9CC01768B
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