Issue 38, 2019
From the journal:

Chemical Communications

Crystal melting and glass formation in copper thiocyanate based coordination polymers†

Sanjog S. Nagarkar, ORCID logo a   Haruna Kurasho,b   Nghia Tuan Duong, ORCID logo c   Yusuke Nishiyama, ORCID logo *cd   Susumu Kitagawae  and  Satoshi Horike ORCID logo *abef  

* Corresponding authors

a AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory (ChEM-OIL), National Institute of Advanced Industrial Science and Technology (AIST), Yoshida-Honmachi, Sakyo-ku, Kyoto 606-8501, Japan

b Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

c NMR Science and Development Division, RIKEN SPring-8 Center and Nano-Crystallography Unit, RIKEN-JEOL Collaboration Center, Tsurumi, Yokohama, Kanagawa 230-0045, Japan
E-mail: yunishiy@jeol.co.jp

d JEOL RESONANCE Inc., 3-1-2 Musashino, Akishima, Tokyo 196-8558, Japan

e Institute for Integrated Cell-Material Sciences, Institute for Advanced Study, Kyoto University, Yoshida-Honmachi, Sakyo-ku, Kyoto 606-8501, Japan

f Department of Materials Science and Engineering, School of Molecular Science and Engineering, Vidyasirimedhi Institute of Science and Technology, Rayong 21210, Thailand

Abstract

Crystal melting and glass formation of coordination polymers (CPs) and metal–organic frameworks (MOFs) are rare thermal events. To expand the library of melting CP/MOFs, we utilized anti-crystal engineering in ionic liquids to construct CPs. A combination of Cu+ and 4,4′-bipyridin-1-ium derivatives afforded four melting CPs showing stable liquid and glassy states.

Graphical abstract: Crystal melting and glass formation in copper thiocyanate based coordination polymers

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Article information

DOI
https://doi.org/10.1039/C9CC02172H
Article type
Communication
Submitted
19 Mar 2019
Accepted
10 Apr 2019
First published
10 Apr 2019

Chem. Commun., 2019,55, 5455-5458

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Crystal melting and glass formation in copper thiocyanate based coordination polymers

S. S. Nagarkar, H. Kurasho, N. T. Duong, Y. Nishiyama, S. Kitagawa and S. Horike, Chem. Commun., 2019, 55, 5455 DOI: 10.1039/C9CC02172H

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