Issue 49, 2019

Single-component frameworks for heterogeneous catalytic hydrolysis of organophosphorous compounds in pure water

Abstract

Amine modified Zr6-based metal–organic frameworks (MOFs) were synthesized through solvent-assisted linker incorporation (SALI) and utilized as single-component heterogeneous catalysts for the hydrolysis of organophosphorous compounds under solely aqueous conditions at room temperature. These materials display unprecidentedly fast catalytic hydrolysis for dimethyl p-nitrophenyl phosphate (DMNP) and nerve agent VX without the use of a buffered solution.

Graphical abstract: Single-component frameworks for heterogeneous catalytic hydrolysis of organophosphorous compounds in pure water

Supplementary files

Article information

Article type
Communication
Submitted
21 Mar 2019
Accepted
16 May 2019
First published
16 May 2019

Chem. Commun., 2019,55, 7005-7008

Author version available

Single-component frameworks for heterogeneous catalytic hydrolysis of organophosphorous compounds in pure water

S. J. Garibay, O. K. Farha and J. B. DeCoste, Chem. Commun., 2019, 55, 7005 DOI: 10.1039/C9CC02236H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements