A robust etb-type metal–organic framework showing polarity-exclusive adsorption of acetone over methanol for their azeotropic mixture

Han Hu; Jiaxing Zhu; Feilong Yang; Zhenxia Chen; Mingli Deng; Linhong Weng; Yun Ling; Yaming Zhou

doi:10.1039/C9CC02439E

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A robust etb-type metal–organic framework showing polarity-exclusive adsorption of acetone over methanol for their azeotropic mixture†

Han Hu,^a Jiaxing Zhu,

^a Feilong Yang,^a Zhenxia Chen,^a Mingli Deng,^a Linhong Weng,^a Yun Ling

*^a and Yaming Zhou^a

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* Corresponding authors

^a Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai, China
E-mail: yunling@fudan.edu.cn

Abstract

We report a robust and rigid etb-type metal–organic framework, in which its pore surface is decorated with flexible ethoxyl groups. It shows unprecedentedly selective adsorption of acetone (E^T_N value of 0.355, kinetic diameter of 4.6 Å) over methanol (E^T_N value of 0.762, kinetic diameter of 3.6 Å) for their azeotropic mixture.

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DOI: https://doi.org/10.1039/C9CC02439E
Article type: Communication
Submitted: 29 Mar 2019
Accepted: 25 Apr 2019
First published: 03 May 2019

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Chem. Commun., 2019,55, 6495-6498

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A robust etb-type metal–organic framework showing polarity-exclusive adsorption of acetone over methanol for their azeotropic mixture

H. Hu, J. Zhu, F. Yang, Z. Chen, M. Deng, L. Weng, Y. Ling and Y. Zhou, Chem. Commun., 2019, 55, 6495 DOI: 10.1039/C9CC02439E

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Chemical Communications

A robust etb-type metal–organic framework showing polarity-exclusive adsorption of acetone over methanol for their azeotropic mixture†

Abstract

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A robust etb-type metal–organic framework showing polarity-exclusive adsorption of acetone over methanol for their azeotropic mixture

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