Nickel(II)-catalyzed direct olefination of benzyl alcohols with sulfones with the liberation of H2

Vinod G. Landge; Vinita Yadav; Murugan Subaramanian; Pragya Dangarh; Ekambaram Balaraman

doi:10.1039/C9CC02603G

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Nickel(ii)-catalyzed direct olefination of benzyl alcohols with sulfones with the liberation of H₂†

Vinod G. Landge,‡^a Vinita Yadav,

‡^ab Murugan Subaramanian,^c Pragya Dangarh^a and Ekambaram Balaraman

*^c

Author affiliations

* Corresponding authors

^a Organic Chemistry Division, CSIR-National Chemical Laboratory (CSIR-NCL), Dr Homi Bhabha Road, Pune-411008, India

^b Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India

^c Department of Chemistry, Indian Institute of Science Education and Research – Tirupati (IISER-Tirupati), Tirupati 517507, India
E-mail: eb.raman@iisertirupati.ac.in

Abstract

A nickel(II)-catalyzed direct olefination of benzyl alcohols with sulfones to access various terminal and internal olefins with the liberation of hydrogen gas is reported.

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Article information

DOI: https://doi.org/10.1039/C9CC02603G
Article type: Communication
Submitted: 03 Apr 2019
Accepted: 29 Apr 2019
First published: 30 Apr 2019

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Chem. Commun., 2019,55, 6130-6133

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Nickel(II)-catalyzed direct olefination of benzyl alcohols with sulfones with the liberation of H₂

V. G. Landge, V. Yadav, M. Subaramanian, P. Dangarh and E. Balaraman, Chem. Commun., 2019, 55, 6130 DOI: 10.1039/C9CC02603G

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