Issue 53, 2019
From the journal:

Chemical Communications

Probing the existence of uranyl trisulfate structures in the AMEX solvent extraction process†

Tamir Sukhbaatar,a   Magali Duvail, ORCID logo a   Thomas Dumas, ORCID logo b   Sandrine Dourdain, ORCID logo *a   Guilhem Arrachart, ORCID logo a   Pier Lorenzo Solari,c   Philippe Guilbaud ORCID logo b  and  Stéphane Pellet-Rostainga  

* Corresponding authors

a ICSM, CEA, CNRS, ENSCM, Univ Montpellier, Marcoule, France
E-mail: sandrine.dourdain@cea.fr
Fax: +33 4 66 79 76 11
Tel: +33 4 66 33 93 09

b CEA, DEN, MAR, DMRC, SPDS, LILA, F-30207 Bagnols-sur-Cèze Cedex, France

c Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin – BP 48, 91192 Gif-sur-Yvette Cedex, France

Abstract

Knowledge of the complex microstructure in solvent extraction phases is mandatory for a full comprehension of ionic separation. Coupling EXAFS with MD simulations for uranyl extraction in sulfuric media with tertiary amine extractants enabled unravelling of the unprecedented uranyl tri-sulfate structure.

Graphical abstract: Probing the existence of uranyl trisulfate structures in the AMEX solvent extraction process

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Article information

DOI
https://doi.org/10.1039/C9CC02651G
Article type
Communication
Submitted
05 Apr 2019
Accepted
30 May 2019
First published
03 Jun 2019

Chem. Commun., 2019,55, 7583-7586

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Probing the existence of uranyl trisulfate structures in the AMEX solvent extraction process

T. Sukhbaatar, M. Duvail, T. Dumas, S. Dourdain, G. Arrachart, P. L. Solari, P. Guilbaud and S. Pellet-Rostaing, Chem. Commun., 2019, 55, 7583 DOI: 10.1039/C9CC02651G

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