Issue 53, 2019

Atomic-layer-deposition-formed sacrificial template for the construction of an MIL-53 shell to increase selectivity of hydrogenation reactions

Abstract

We developed a method for using atomic layer deposition (ALD)-formed layers of Al2O3 as a sacrificial template to generate MIL-53(Al). The MOF shell in the CeO2/Pd@MIL-53(Al) configuration not only stabilized the Pd nanoparticles, but also regulated the selectivity of the hydrogenation of unsaturated aldehydes. This work represents the first demonstration of ALD-formed layers of metal oxides serving as sacrificial templates in the design of MOF-shell-based sandwich-type structures.

Graphical abstract: Atomic-layer-deposition-formed sacrificial template for the construction of an MIL-53 shell to increase selectivity of hydrogenation reactions

Supplementary files

Article information

Article type
Communication
Submitted
09 Apr 2019
Accepted
05 Jun 2019
First published
05 Jun 2019

Chem. Commun., 2019,55, 7651-7654

Atomic-layer-deposition-formed sacrificial template for the construction of an MIL-53 shell to increase selectivity of hydrogenation reactions

T. Xu, K. Sun, D. Gao, C. Li, X. Hu and G. Chen, Chem. Commun., 2019, 55, 7651 DOI: 10.1039/C9CC02727K

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