(H3O)HCs2Nb(IO3)9 and SrNbO(IO3)5: a facile synthetic method using hydrofluoric acid as a solubilizer†
Abstract
By using hydrofluoric acid as a solubilizer, the first alkali-metal niobium iodate and an alkali-earth metal niobium iodate, i.e. (H3O)HCs2Nb(IO3)9 and SrNbO(IO3)5, have been obtained. An obvious cation-controlled polarity shift is observed in the Ae/A-Nb5+-IO3 system. (H3O)HCs2Nb(IO3)9 gives a strong second harmonic generation (SHG) signal about 6 times that of KH2PO4 (KDP), making it a promising nonlinear optical (NLO) material.