Issue 46, 2019
From the journal:

Chemical Communications

Chain length effect in the functionalization of polyoxometalates with α,ω-alkyldiphosphonates†

Zhiwei Liu,a   Wei Wang,b   Jinkui Tang, ORCID logo c   Weiqi Li,d   Weiye Yina  and  Xikui Fang ORCID logo *a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China
E-mail: xkfang@hit.edu.cn

b Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou 350002, China

c State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

d School of Physics, Harbin Institute of Technology, Harbin 150001, China

Abstract

Altering the organic spacers in hybrid complexes of polyoxotungstates and long-chain α,ω-alkyldiphosphonates (Ln), by a single CH2 group (e.g.L6vs.L5), can steer the self-assembly processes into different paths. Even homologous hybrids of L5 and L4 have seen the spin ground states switch from S = 0 to S = 9 upon shortening the chain length (L5vs.L4).

Graphical abstract: Chain length effect in the functionalization of polyoxometalates with α,ω-alkyldiphosphonates

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Article information

DOI
https://doi.org/10.1039/C9CC02854D
Article type
Communication
Submitted
12 Apr 2019
Accepted
13 May 2019
First published
13 May 2019

Chem. Commun., 2019,55, 6547-6550

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Chain length effect in the functionalization of polyoxometalates with α,ω-alkyldiphosphonates

Z. Liu, W. Wang, J. Tang, W. Li, W. Yin and X. Fang, Chem. Commun., 2019, 55, 6547 DOI: 10.1039/C9CC02854D

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