Issue 60, 2019

Cooperative activation of X–H (X = H, C, O, N) bonds by a Pt(0)/Ag(i) metal-only Lewis pair

Abstract

Metal-only Lewis pairs made of Pt(0)/Ag(I) combinations have been previously reported, but their cooperative reactivity remains unexplored. Here we demonstrate that these systems are capable of synergistically activating a wide variety of X–H (X = H, C, O, N) bonds, including those in dihydrogen, alkynes, water and ammonia.

Graphical abstract: Cooperative activation of X–H (X = H, C, O, N) bonds by a Pt(0)/Ag(i) metal-only Lewis pair

Supplementary files

Article information

Article type
Communication
Submitted
17 Apr 2019
Accepted
17 May 2019
First published
17 May 2019
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2019,55, 8812-8815

Cooperative activation of X–H (X = H, C, O, N) bonds by a Pt(0)/Ag(I) metal-only Lewis pair

N. Hidalgo, C. Maya and J. Campos, Chem. Commun., 2019, 55, 8812 DOI: 10.1039/C9CC03008E

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