Issue 75, 2019
From the journal:

Chemical Communications

Assessing the impacts of dynamic soft-templates innate to switchable ionic liquids on nanoparticulate green rust crystalline structures†

Jian Zheng, ORCID logo a   Xiao-Ying Yu, ORCID logo *b   Manh-Thuong Nguyen,a   David Lao,b   Yifeng Zhu,a   Feng Wangc  and  David J. Heldebrant ORCID logo *b  

* Corresponding authors

a Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, WA 99354, USA

b Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, WA 99354, USA
E-mail: xiaoying.yu@pnnl.gov, david.heldebrant@pnnl.gov

c Sustainable Energy Technologies Department, Brookhaven National Laboratory, Upton, NY 11973, USA

Abstract

This experimental and theoretical study investigates how dynamic solvation environments in switchable ionic liquids regulate the composition of nanoparticulate green rust. A custom microfluidic device enables in situ X-ray absorption spectroscopy to elucidate characterization of the solvent structure and speciation of reaction intermediates of air-sensitive nanoparticles growing in solution.

Graphical abstract: Assessing the impacts of dynamic soft-templates innate to switchable ionic liquids on nanoparticulate green rust crystalline structures

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Article information

DOI
https://doi.org/10.1039/C9CC04581C
Article type
Communication
Submitted
14 Jun 2019
Accepted
19 Aug 2019
First published
30 Aug 2019

Chem. Commun., 2019,55, 11239-11242

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Assessing the impacts of dynamic soft-templates innate to switchable ionic liquids on nanoparticulate green rust crystalline structures

J. Zheng, X. Yu, M. Nguyen, D. Lao, Y. Zhu, F. Wang and D. J. Heldebrant, Chem. Commun., 2019, 55, 11239 DOI: 10.1039/C9CC04581C

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