Issue 91, 2019
From the journal:

Chemical Communications

Thermodynamic control of quantum defects on single-walled carbon nanotubes†

Yutaka Maeda, ORCID logo *a   Hiyori Murakoshi,a   Haruto Tambo,a   Pei Zhao, ORCID logo b   Kiyonori Kuroda,a   Michio Yamada, ORCID logo a   Xiang Zhao, ORCID logo c   Shigeru Nagase ORCID logo d  and  Masahiro Ehara ORCID logo *b  

* Corresponding authors

a Department of Chemistry, Tokyo Gakugei University, Tokyo 184-8501, Japan
E-mail: ymaeda@u-gakugei.ac.jp

b Research Center for Computational Science, Institute for Molecular Science, Okazaki, Japan
E-mail: ehara@ims.ac.jp

c Institute for Chemical Physics & Department of Chemistry, School of Science, State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an 710049, China

d Fukui Institute for Fundamental Chemistry (FIFC), Kyoto University, Sakyou-ku, Kyoto 606-8103, Japan

Abstract

Single-walled carbon nanotubes with designed quantum defects are prepared and characterized. The photoluminescence (PL) of the nanotubes can be modified by thermal treatment from 1215–1224 to 1249–1268 nm. Theoretical calculations suggest that the change in the PL spectra by thermal treatment can be explained by isomerization from kinetic to thermodynamic products.

Graphical abstract: Thermodynamic control of quantum defects on single-walled carbon nanotubes

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Article information

DOI
https://doi.org/10.1039/C9CC05623H
Article type
Communication
Submitted
20 Jul 2019
Accepted
21 Oct 2019
First published
23 Oct 2019

Chem. Commun., 2019,55, 13757-13760

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Thermodynamic control of quantum defects on single-walled carbon nanotubes

Y. Maeda, H. Murakoshi, H. Tambo, P. Zhao, K. Kuroda, M. Yamada, X. Zhao, S. Nagase and M. Ehara, Chem. Commun., 2019, 55, 13757 DOI: 10.1039/C9CC05623H

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