Rhodium catalyzed C–C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates and analogs

Xuan Yang; Wei-Yu Kong; Jia-Ni Gao; Li Cheng; Nan-Nan Li; Meng Li; Hui-Ting Li; Jun Fan; Jin-Ming Gao; Qin Ouyang; Jian-Bo Xie

doi:10.1039/C9CC06446J

Rhodium catalyzed C–C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates and analogs†

Xuan Yang,

^a Wei-Yu Kong,^a Jia-Ni Gao,^a Li Cheng,^b Nan-Nan Li,^a Meng Li,^a Hui-Ting Li,^a Jun Fan,^a Jin-Ming Gao,

^a Qin Ouyang

*^c and Jian-Bo Xie

*^ab

Author affiliations

* Corresponding authors

^a Shaanxi Key Laboratory of Natural Products & Chemical Biology, College of Chemistry & Pharmacy, Northwest A&F University, Yangling 712100, China
E-mail: jianbo_xie@nwafu.edu.cn

^b State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

^c College of Pharmacy, Third Military Medical University, Chongqing 400038, China
E-mail: ouyangq@tmmu.edu.cn

Abstract

The C–C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates with aryl boronic acids catalyzed by a rhodium complex was studied with a “conjugate addition/β-C cleavage/protonation” strategy.

Chemical Communications

Rhodium catalyzed C–C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates and analogs†

Abstract

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Rhodium catalyzed C–C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates and analogs

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