Issue 95, 2019
From the journal:

Chemical Communications

The first two examples of halogen bonding with a sigma hole-donating fluorine in the Csp3–F⋯Osp3 interaction from polyfluorinated trans-dihalo-palladium(ii) di-substituted pyridine complexes†

Vijayanath Elakkat,a   Chu-Chun Chang,a   Jun-Yu Chen,a   Yung-Cheng Fang,a   Chia-Rui Shen, ORCID logo *b   Ling-Kung Liu ORCID logo ac  and  Norman Lu ORCID logo *a  

* Corresponding authors

a Institute of Organic and Polymeric Materials, National Taipei Univ of Technology, Taipei 106, Taiwan
E-mail: normanlu@mail.ntut.edu.tw

b Chang Gung University and Linkou Chang Gung Memorial Hospital, Kweishan, Taoyuan 333, Taiwan
E-mail: crshen@mail.cgu.edu.tw

c Institute of Chemistry, Academia Sinica, 115 Nankang, Taipei, Taiwan, Republic of China

Abstract

The first two examples of halogen bonding in the Csp3–F⋯Osp3 interaction have been both experimentally and theoretically proved for trans-[PdX2(3-HCF2CF2CH2OCH2py)2] complexes where X = Cl and Br. Both metal complexes with a Csp3–F⋯Osp3 halogen bond have a σ hole donating fluorine.

Graphical abstract: The first two examples of halogen bonding with a sigma hole-donating fluorine in the Csp3–F⋯Osp3 interaction from polyfluorinated trans-dihalo-palladium(ii) di-substituted pyridine complexes

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Article information

DOI
https://doi.org/10.1039/C9CC06731K
Article type
Communication
Submitted
29 Aug 2019
Accepted
15 Oct 2019
First published
15 Oct 2019

Chem. Commun., 2019,55, 14259-14262

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The first two examples of halogen bonding with a sigma hole-donating fluorine in the Csp3–F⋯Osp3 interaction from polyfluorinated trans-dihalo-palladium(II) di-substituted pyridine complexes

V. Elakkat, C. Chang, J. Chen, Y. Fang, C. Shen, L. Liu and N. Lu, Chem. Commun., 2019, 55, 14259 DOI: 10.1039/C9CC06731K

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