Herein we report for the first time the site-selective C–H bond arylation of tryptophan and tryptophan residues in proteins in aqueous media at room temperature by using a PdNP bionanohybrid as a heterogeneous catalyst. The reaction proceeds using a stable aryldiazonium salt without a base.
C. Perez-Rizquez, O. Abian and J. M. Palomo, Chem. Commun., 2019, 55, 12928 DOI: 10.1039/C9CC06971B
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