Issue 86, 2019
From the journal:

Chemical Communications

Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol†

Giulia Magnabosco, ORCID logo a   Andrea M. M. Condorelli,a   Rose Rosenberg,b   Iryna Polishchuk,c   Boaz Pokroy, ORCID logo c   Denis Gebauer,b   Helmut Cölfen ORCID logo *b  and  Giuseppe Falini ORCID logo *a  

* Corresponding authors

a Dipartimento di Chimica “Giacomo Ciamician”, Alma Mater Studiorum Università di Bologna, via F. Selmi 2, 40126 Bologna, Italy
E-mail: Giuseppe.falini@unibo.it

b Department of Chemistry, Physical Chemistry, Universität Konstanz, Universitätsstraße 10, D-78457 Konstanz, Germany

c Department of Material Sciences, Technion-Israel Institute of Technology, 43000 Haifa, Israel

Abstract

The effect of Mg2+ on the precipitation pathway of CaCO3 in absolute ethanol has been studied to investigate the role of ion solvation in the crystallization process. Our data reveal that high concentrations of Mg2+ promote the precipitation of an amorphous transient phase together with non-stoichometric hydrated phases of calcium carbonate.

Graphical abstract: Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol

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Article information

DOI
https://doi.org/10.1039/C9CC07087G
Article type
Communication
Submitted
10 Sep 2019
Accepted
03 Oct 2019
First published
03 Oct 2019

Chem. Commun., 2019,55, 12944-12947

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Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol

G. Magnabosco, A. M. M. Condorelli, R. Rosenberg, I. Polishchuk, B. Pokroy, D. Gebauer, H. Cölfen and G. Falini, Chem. Commun., 2019, 55, 12944 DOI: 10.1039/C9CC07087G

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