Issue 93, 2019
From the journal:

Chemical Communications

Double spin crossovers: a new double salt strategy to improve magnetic and memory properties†

Wasinee Phonsri, ORCID logo a   Barnaby A. I. Lewis,ab   Guy N. L. Jameson ORCID logo c  and  Keith S. Murray ORCID logo *a  

* Corresponding authors

a School of Chemistry, Monash University, 17 Rainforest Walk, Clayton, VIC 3800, Australia
E-mail: keith.murray@monash.edu

b Department of Chemistry, University of Warwick, Coventry, UK

c School of Chemistry, Bio21 Molecular Science and Biotechnology Institute, The University of Melbourne, 30 Flemington Road, Parkville, VIC 3010, Australia

Abstract

The structural, magnetic and Mössbauer spectral properties of a double salt, mixed-valent material, [FeII(3,5-Me2TPM)(TPM)][FeIII(azp)2]ClO4·2MeCN, 1, reveal spin transitions occur at both the metal sites, with hysteresis, indicative of 1 being a double spin crossover material.

Graphical abstract: Double spin crossovers: a new double salt strategy to improve magnetic and memory properties

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Article information

DOI
https://doi.org/10.1039/C9CC07416C
Article type
Communication
Submitted
21 Sep 2019
Accepted
28 Oct 2019
First published
29 Oct 2019

Chem. Commun., 2019,55, 14031-14034

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Double spin crossovers: a new double salt strategy to improve magnetic and memory properties

W. Phonsri, B. A. I. Lewis, G. N. L. Jameson and K. S. Murray, Chem. Commun., 2019, 55, 14031 DOI: 10.1039/C9CC07416C

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