Cold crystallization in the mixed system of adenine and thymine dodecyl derivatives

Ayaka Kimijima; Akinori Honda; Kuniharu Nomoto; Kazuo Miyamura

doi:10.1039/C9CE00407F

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Cold crystallization in the mixed system of adenine and thymine dodecyl derivatives†

Ayaka Kimijima,

*^a Akinori Honda,

‡^a Kuniharu Nomoto^a and Kazuo Miyamura*^a

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* Corresponding authors

^a Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan
E-mail: 1317643@ed.tus.ac.jp, miyamura@rs.kagu.tus.ac.jp

Abstract

The 1 : 1 mixture of adenine and thymine both substituted with dodecyl groups exhibited supercooling and heat storage phenomena including cold crystallization. The unique flexible π-conjugated cores formed through complementary hydrogen bonds with reverse Hoogsteen patterns induced the curious thermal behavior.

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DOI: https://doi.org/10.1039/C9CE00407F
Article type: Communication
Submitted: 20 Mar 2019
Accepted: 24 Apr 2019
First published: 26 Apr 2019

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CrystEngComm, 2019,21, 3142-3145

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Cold crystallization in the mixed system of adenine and thymine dodecyl derivatives

A. Kimijima, A. Honda, K. Nomoto and K. Miyamura, CrystEngComm, 2019, 21, 3142 DOI: 10.1039/C9CE00407F

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CrystEngComm

Cold crystallization in the mixed system of adenine and thymine dodecyl derivatives†

Abstract

Supplementary files

Article information

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Cold crystallization in the mixed system of adenine and thymine dodecyl derivatives

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