A combination of electrospray-ionization mass spectrometry and Mössbauer spectroscopy was used to investigate the species generated in situ in highly enantioselective Fe/NHC-catalyzed C–H alkylations. The findings indicate an organometallic iron(II)–NHC species to be of key relevance in the asymmetric catalysis.
J. Loup, T. Parchomyk, S. Lülf, S. Demeshko, F. Meyer, K. Koszinowski and L. Ackermann, Dalton Trans., 2019, 48, 5135 DOI: 10.1039/C9DT00705A
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