Decanuclear FeIII clusters with hemiacetal ligands: a new {M10(μ3-O)8} cluster core

J. Mayans; L. Roc; M. Font-Bardia; A. Escuer

doi:10.1039/C9DT01568J

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Decanuclear Fe^III clusters with hemiacetal ligands: a new {M₁₀(μ₃-O)₈} cluster core†

J. Mayans,^a L. Roc,^a M. Font-Bardia^b and A. Escuer

*^a

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* Corresponding authors

^a Departament de Química Inorgànica i Orgànica, Secció Inorgànica and Institute of Nanoscience (IN2UB) and Nanotecnology, Universitat de Barcelona, Martí i Franquès 1-11, Barcelona-08028, Spain
E-mail: albert.escuer@qi.ub.es

^b Departament de Mineralogia, Cristal·lografia i Dipòsits Minerals and Unitat de Difracció de R-X. Centre Científic i Tecnològic de la Universitat de Barcelona (CCiTUB), Universitat de Barcelona, Solé i Sabarís 1-3, 08028 Barcelona, Spain

Abstract

The characterization of a decanuclear Fe^III cluster with α-methyl-2-pyridinemethanolate, generated by the hydrolysis of Schiff bases, inspired us to carry out an initial exploration of the direct syntheses of medium nuclearity Fe^III clusters starting from aldehydes in methanolic medium. The new complexes exhibit an unprecedented {Fe₁₀(μ₃-O)₈} cluster core.

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Article information

DOI: https://doi.org/10.1039/C9DT01568J
Article type: Communication
Submitted: 12 Apr 2019
Accepted: 01 Jul 2019
First published: 01 Jul 2019

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Dalton Trans., 2019,48, 13139-13142

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Decanuclear Fe^III clusters with hemiacetal ligands: a new {M₁₀(μ₃-O)₈} cluster core

J. Mayans, L. Roc, M. Font-Bardia and A. Escuer, Dalton Trans., 2019, 48, 13139 DOI: 10.1039/C9DT01568J

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Dalton Transactions