Alkaline-earth metallacyclic complexes bearing a diborane-bridged tetraamide ligand: synthesis, structure and fluorescence property

Abstract

A series of alkaline–earth (Mg, Ca, and Sr) metallacyclic complexes bearing a diborane-bridged tetraamide ligand were achieved for the first time through a clean one-step approach. All of these metallacycles were characterized by single-crystal X-ray diffraction analyses. UV-Vis absorption/emission spectroscopy showed deep blue fluorescence of these complexes.