Issue 35, 2019
From the journal:

Dalton Transactions

Cluster–oxalate frameworks with extra-large channels: solvent-free synthesis, chemical stability, and proton conduction†

Lindong Luan, ORCID logo ab   Ying Zhang,a   Hongmei Zeng,a   Guohong Zou, ORCID logo a   Yong Dai,b   Xiaoying Zhou*b  and  Zhien Lin ORCID logo *a  

* Corresponding authors

a College of Chemistry, Sichuan University, Chengdu 610064, P. R. China
E-mail: zhienlin@scu.edu.cn

b Department of Criminal Science and Technology, Sichuan Police College, Luzhou 646000, P. R. China
E-mail: 907287136@qq.com

Abstract

Two cluster–oxalate frameworks (denoted as SCU-62 and SCU-65) were prepared under solvent-free conditions. They contain extra-large 16-ring channels constructed from regular Mn6(SO4)6 double six-ring units (D6Rs) and lacunary In5(HPO4)6 D6Rs, respectively. Notably, SCU-65 remains stable in both boiling water and aqueous solutions with a pH range of 3–12. It has a proton conductivity of 5.5 × 10−5 S cm−1 at 85 °C under 95% relative humidity.

Graphical abstract: Cluster–oxalate frameworks with extra-large channels: solvent-free synthesis, chemical stability, and proton conduction

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Article information

DOI
https://doi.org/10.1039/C9DT02703C
Article type
Communication
Submitted
28 Jun 2019
Accepted
28 Jul 2019
First published
29 Jul 2019

Dalton Trans., 2019,48, 13130-13134

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Cluster–oxalate frameworks with extra-large channels: solvent-free synthesis, chemical stability, and proton conduction

L. Luan, Y. Zhang, H. Zeng, G. Zou, Y. Dai, X. Zhou and Z. Lin, Dalton Trans., 2019, 48, 13130 DOI: 10.1039/C9DT02703C

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