Inter-ligand delocalisations in transition metal complexes containing multiple non-innocent ligands

Ho Chuen Wan; Jing-Xuan Zhang; Chung Sum Leung; Fu Kit Sheong; Zhenyang Lin

doi:10.1039/C9DT02806D

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Inter-ligand delocalisations in transition metal complexes containing multiple non-innocent ligands†‡

Ho Chuen Wan,§^a Jing-Xuan Zhang,

§^a Chung Sum Leung,^a Fu Kit Sheong

*^ab and Zhenyang Lin

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong
E-mail: fksheong@connect.ust.hk, chzlin@ust.hk

^b Institute for Advanced Study, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong

Abstract

Systematic bonding analysis has been carried out for transition metal complexes containing more than one redox-active/non-innocent ligand. These complexes include tetralithio spiroaromatic palladole, dicupra[10]annulene, highly reduced nickel cyclooctadiene complex and tris(dithiolene)vanadium(IV). Our detailed bonding analysis reveals a common inter-ligand delocalisation pattern in these cases.

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DOI: https://doi.org/10.1039/C9DT02806D
Article type: Paper
Submitted: 06 Jul 2019
Accepted: 06 Sep 2019
First published: 09 Sep 2019

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Dalton Trans., 2019,48, 14801-14807

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Inter-ligand delocalisations in transition metal complexes containing multiple non-innocent ligands

H. C. Wan, J. Zhang, C. S. Leung, F. K. Sheong and Z. Lin, Dalton Trans., 2019, 48, 14801 DOI: 10.1039/C9DT02806D

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Dalton Transactions

Inter-ligand delocalisations in transition metal complexes containing multiple non-innocent ligands†‡

Abstract

Supplementary files

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Inter-ligand delocalisations in transition metal complexes containing multiple non-innocent ligands

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