Issue 37, 2019
From the journal:

Dalton Transactions

Sub-nanometer Cu(i) clusters: coordination-modulated (Se vs. S) atom-packing mode and emission†

Feng Ke,ab   Yongbo Song, ORCID logo *ab   Hao Li,ab   Chuanjun Zhou,ab   Yuanxin Duab  and  Manzhou Zhu ORCID logo *ab  

* Corresponding authors

a Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui 230601, People's Republic of China
E-mail: ybsong860@ahu.edu.cn, zmz@ahu.edu.cn

b Key Laboratory of Structure and Functional Regulation of Hybrid Materials, Anhui University, Ministry of Education, Hefei, Anhui 230601, People's Republic of China

Abstract

Herein, the ligands’ effect in Cu(I) clusters was initially explored. The results demonstrate that the Se atom possesses more coordination modes with Cu (μ2, μ3, μ4, μ6) than S, which significantly modulates the atom-packing mode of Cu(I) clusters. Importantly, this also endows these clusters with different temperature-dependent luminescent behaviours.

Graphical abstract: Sub-nanometer Cu(i) clusters: coordination-modulated (Se vs. S) atom-packing mode and emission

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Article information

DOI
https://doi.org/10.1039/C9DT02908G
Article type
Communication
Submitted
15 Jul 2019
Accepted
27 Aug 2019
First published
27 Aug 2019

Dalton Trans., 2019,48, 13921-13924

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Sub-nanometer Cu(I) clusters: coordination-modulated (Se vs. S) atom-packing mode and emission

F. Ke, Y. Song, H. Li, C. Zhou, Y. Du and M. Zhu, Dalton Trans., 2019, 48, 13921 DOI: 10.1039/C9DT02908G

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