Issue 5, 2019

Seaming the interfaces between topologically distinct metal–organic frameworks using random copolymer glues

Abstract

Creating novel and multifunctional MOF-on-MOF hetero-architectures to achieve desired properties is a new frontier in MOF research. Herein, we demonstrate a generalizable method to construct core–shell MOFs using rationally designed random copolymer (RCP) glues as mediators to seam the interfaces between MOFs with mismatched topologies and coordination chemistry. The key advantage of this method is that the composition and functionality of the RCPs can be systematically tuned through judicious monomer selection to optimize the shell quality and potentially meet the demand for different core–shell MOFs.

Graphical abstract: Seaming the interfaces between topologically distinct metal–organic frameworks using random copolymer glues

Associated articles

Supplementary files

Article information

Article type
Communication
Submitted
04 Dec 2018
Accepted
06 Jan 2019
First published
09 Jan 2019

Nanoscale, 2019,11, 2121-2125

Seaming the interfaces between topologically distinct metal–organic frameworks using random copolymer glues

F. Wang, H. Wang and T. Li, Nanoscale, 2019, 11, 2121 DOI: 10.1039/C8NR09777A

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