Issue 20, 2019

Deformation induced new pathways in silicon

Abstract

No in situ nanomechanical tests on damaged brittle materials have been demonstrated. This means that the transition route in damaged silicon (Si) under deformation is elusive. A gap is formed between abrasive machining and present nanomechanical tests, due to the unmatched nanostructure produced. In this study, a Si wedge is fabricated with a plateau of 80 nm in thickness. In situ dynamic nanoindentation is performed in a transmission electron microscope (TEM) on the damaged Si wedge, using a developed cube corner indenter with a tip radius of 66 nm. Nanotwins, slip bands and intersected stacking faults are observed in Si, which bridge the gap between abrasive machining and nanomechanical tests. A transition from Si-I to Si-VI is demonstrated by in situ atomic characterization, which is a new pathway in Si induced by in situ TEM nanoindentation. Ab initio calculations are conducted to elucidate the transition mechanism from Si-I to Si-VI. In the transition, the average potential energy is increased by 1.21 eV, and the average force exerted on an atom is 2.444 nN through compression and rotation. The findings propose new insights into the fabrication of high-performance devices and nanostructures in the electronics industry.

Graphical abstract: Deformation induced new pathways in silicon

Supplementary files

Article information

Article type
Paper
Submitted
18 Feb 2019
Accepted
14 Mar 2019
First published
27 Mar 2019

Nanoscale, 2019,11, 9862-9868

Deformation induced new pathways in silicon

Z. Zhang, J. Cui, K. Chang, D. Liu, G. Chen, N. Jiang and D. Guo, Nanoscale, 2019, 11, 9862 DOI: 10.1039/C9NR01478K

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