Issue 18, 2019

Chiral benzazaboroles as catalysts for enantioselective sulfonylation of cis-1,2-diols

Abstract

A newly developed benzazaborole smoothly catalyzed the enantioselective sulfonylation of cis-1,2-diols. Using a chiral benzazaborole/NMI co-catalyst system, various sulfonate esters were prepared in high yields with good enantioselectivities.

Graphical abstract: Chiral benzazaboroles as catalysts for enantioselective sulfonylation of cis-1,2-diols

Supplementary files

Article information

Article type
Paper
Submitted
26 Dec 2018
Accepted
13 Mar 2019
First published
14 Mar 2019

Org. Biomol. Chem., 2019,17, 4475-4482

Chiral benzazaboroles as catalysts for enantioselective sulfonylation of cis-1,2-diols

S. Kuwano, Y. Hosaka and T. Arai, Org. Biomol. Chem., 2019, 17, 4475 DOI: 10.1039/C8OB03205J

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